- News Home
17 April 2014 12:48 pm ,
Vol. 344 ,
Officials last week revealed that the U.S. contribution to ITER could cost $3.9 billion by 2034—roughly four times the...
An experimental hepatitis B drug that looked safe in animal trials tragically killed five of 15 patients in 1993. Now,...
Using the two high-quality genomes that exist for Neandertals and Denisovans, researchers find clues to gene activity...
A new report from the Intergovernmental Panel on Climate Change (IPCC) concludes that humanity has done little to slow...
Astronomers have discovered an Earth-sized planet in the habitable zone of a red dwarf—a star cooler than the sun—500...
Three years ago, Jennifer Francis of Rutgers University proposed that a warming Arctic was altering the behavior of the...
- 17 April 2014 12:48 pm , Vol. 344 , #6181
- About Us
Color Breaks Free of Heavy Metal
26 April 2000 7:00 pm
Chemists have found a safe substitute for the brilliant yellow and red cadmium-based pigments used to tint glass and ceramic glazes. The new pigments contain no heavy metals, but are vivid and durable, scientists report in the 27 April issue of Nature. The pigments should be commercially available within a year.
Cadmium pigments are almost completely insoluble, so you won't get cadmium poisoning from drinking coffee out of a glazed mug. But if the mug breaks and you throw it away, the intense heat of the neighborhood incineration plant can free the cadmium, a poisonous metal, and potentially release it into the environment. Most governments strictly regulate the handling of cadmium pigments, but they are still used to tint glasses, glazes, and ceramics because there has been no safer alternative.
To create a substitute, chemists Martin Jansen and H. P. Letschert of the Max Planck Institute in Stuttgart, Germany, mixed solid calcium and lanthanum in a hot stream of gaseous ammonia--a mix they knew would create bright colors. They systematically varied the relative proportion of calcium and lanthanum in the mixture. This tuned the oxygen-to-nitrogen ratio in the resulting solid to anywhere between 0.5 and 2, creating colors ranging from bright yellow to deep red. The palette precisely matches the colors of the cadmium-based pigments. Although these nontoxic pigments are 20 times more expensive than the old ones, Jansen is confident that consumers will want an environmentally friendly glaze. He estimates that the premium pigment would only add about 10 cents to the price of a dish.
Frank Di Salvo, a solid state chemist at Cornell University in Ithaca, New York, thinks the new tint will start a wave of innovations in nontoxic inorganic pigments. "This is a great first start," says Di Salvo, "You could eat the stuff and it wouldn't hurt you."